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: MCQs on Basic Concepts of Organic Chemistry
MCQ 1
The unique property of carbon to form long chains is called:
A. Isomerism
B. Catenation
D. Polymerization
✅ Correct Answer: B. Catenation
Explanation:
Carbon atoms can bond with each other strongly due to catenation, allowing the formation of long chains and rings.
MCQ 2
The hybridization of carbon in methane (CH₄) is:
A. sp
B. sp²
C. sp³
D. dsp²
✅ Correct Answer: C. sp³
Explanation:
In methane, carbon forms four single bonds arranged tetrahedrally, indicating sp³ hybridization.
: MCQs on Hydrocarbons (NEET/JEE Level)
MCQ 3
Which hydrocarbon undergoes addition reactions?
A. Alkane
B. Alkene
C. Alkyl halide
D. Alcohol
✅ Correct Answer: B. Alkene
Explanation:
Alkenes contain a C=C double bond, which breaks during addition reactions.
MCQ 4
Which of the following is an unsaturated hydrocarbon?
A. Ethane
B. Propane
C. Ethene
D. Methane
✅ Correct Answer: C. Ethene
Explanation:
Ethene contains a double bond and is therefore an unsaturated hydrocarbon.
: MCQs on Functional Groups
MCQ 5
The functional group present in aldehydes is:
A. –COOH
B. –CO–
C. –CHO
D. –OH
✅ Correct Answer: C. –CHO
Explanation:
Aldehydes are characterized by the presence of the –CHO functional group.
MCQ 6
Which compound will give effervescence with sodium bicarbonate?
A. Alcohol
B. Aldehyde
C. Ketone
✅ Correct Answer: D. Carboxylic acid
Explanation:
Carboxylic acids react with NaHCO₃ to produce CO₂ gas, causing effervescence.
: MCQs on Isomerism
MCQ 7
Isomers have the same:
A. Structural formula
B. Empirical formula
C. Molecular formula
D. Functional group
✅ Correct Answer: C. Molecular formula
Explanation:
Isomers have identical molecular formulas but different arrangements of atoms.
MCQ 8
Chain isomerism is shown by:
A. Ethane
B. Butane
C. Methane
D. Ethene
✅ Correct Answer: B. Butane
Explanation:
Butane exists as n-butane and isobutane, showing chain isomerism.
: MCQs on Alcohols, Aldehydes & Ketones
MCQ 9
Oxidation of a primary alcohol gives:
A. Ketone
B. Ether
C. Aldehyde
D. Alkane
✅ Correct Answer: C. Aldehyde
Explanation:
Primary alcohols oxidize first to aldehydes and then to carboxylic acids.
MCQ 10
Which reagent is used to distinguish aldehyde from ketone?
B. Sodium hydroxide
C. HCl
D. Alcoholic KOH
✅ Correct Answer: A. Fehling’s solution
Explanation:
Aldehydes reduce Fehling’s solution, while ketones do not.
: MCQs on Amines
MCQ 11
The basic nature of amines is due to:
A. Presence of hydrogen
B. Lone pair of electrons on nitrogen
C. High molecular mass
D. Alkyl group
✅ Correct Answer: B. Lone pair of electrons on nitrogen
Explanation:
The lone pair on nitrogen allows amines to accept protons, making them basic.

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